Hydrogen induced cracking hic from advanced ndt solutions. The molecular hydrogen formed in situ produces blisters, and adjacent blisters subsequently are connected on different planes in the metal. Detection, characterization and sizing of hydrogen induced cracking in pressure vessels using phased array ultrasonic data processing article pdf available december 2016 with 380 reads. Hic can be confused with laminations or volumetric inclusions.
Working in over 40 refineries, we are monitoring about 5000 objects for the presence of hic, and for the growth of the hicdamage. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Susceptibility to hydrogeninduced cracking of api 5l b and x52ms lowcarbon. Hydrogen induced cracking hic the base of our company started with hic testing and this is still one of our most requested techniques. Gti gas technology institute gul guided ultrasonic gwut guidedwave ultrasonic testing haz heataffected zone hca highconsequence area hdd horizontally directionally drilled hic hydrogen induced cracking ic internal corrosion icda internal corrosion direct assessment idx integrity data exchange. This site uses cookies and other tracking technologies to provide you with a. Hydrogen damage is the generic name given to a large number of metal degradation processes due to interaction with hydrogen hydrogen is present practically everywhere, several kilometres above the earth and inside the earth. There are ndt techniques focused on identifying, measuring and tracking hic, but total focusing method tfm has shown to be generally the preferred technique. Influence of precipitation behavior on mechanical properties and hydrogen induced cracking during tempering of hotrolled api steel for tubing.
There is a growing acceptance of the term scc to co\er both mechanisms. Volume 2 of gaseous hydrogen embrittlement of materials in energy technologies is an. Detection, characterization and sizing of hydrogen induced. Hydrogen in stress corrosion cracking of x70 pipeline steels in nearneutral ph solutions. A proposal procedure to estimate the hydrogen induced cracking growth rate. Training of personnel in using the modeling schemes. Hydrogen induced cracking hic is a failure mechanism resulting. A comparative study of hydrogeninduced cracking resistances of. Inspection and analysis on samples of hydrogen induced. New concept for cathodic protection of offshore pipelines to reduce hydrogen induced stress cracking hisc in high strength %cr stainless steels. Published by welding technology institute of australia wtia, silverwater, nsw, australia, 1999. Fundamentals of hydrogen embrittlement in steel fasteners s. With the development of oil and gas drilling technology, more and more oil pipes and steel materials used for chemical equipment are servicing in the severe conditions like wet hydrogen sulfide electrolyte. Often occurs as crack colonies that are usually aligned axially on external side of the pipe.
Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Sgs industrial services offers hic monitoring on piping and vessels. Figure 2 fracture surface showing both brittle intergranular morphology resulting from hydrogen induced cracking hic and ductile dimple morphology indicative of final rupture. Hydrogen blistering occurs when hydrogen atoms diffuse into the steel, and hydrogen gas nucleates at internal defects and inclusions, forming voids which eventually generate enough pressure to locally rupture the metal. It is well understood that many environmentally induced cracking requires the confluence of susceptable material stress and corrosive media. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Weld metal hydrogen cracking in pipeline girth welds, proc. Cracking usually occurs at temperatures at or near normal ambient. Ability to map large areas with high speed high resolution data.
Detection of hydrogen induced cracks during inservice inspection of piping using ultrasonic phased arrays assessment of fitness for service. In this issue, the characteristic features and principal causes of hydrogen cracks are described. A number of factors can contribute to their initiation and growth, including highstress, steel susceptibility and corrosive environment in. Hydrogen induced cracking is a mechanical fracture caused by penetration and diffusion of atomic hydrogen into the internal structure of steel, which changes into molecular hydrogen at internal interfaces between nonmetallic inclusions and the base material.
Venizelou, 14452 metamorphosi, athens, greece abstract. Gaseous hydrogen embrittlement of materials in energy technologies mechanisms, modelling and future developments. Presently this phenomenon is not completely understood and hydrogen embrittlement detection, in particular, seems to be one of the most difficult aspects of the problem. Hic small defect detection for carbon steel specimen inspection.
Hydrogen damage takes place at two temperature regions. Athanasios anastasopoulos, lazaros bouchagier, panagiotis kastanis, dimitrios papasalouros, ioannis ladis, dimitrios kourousis mistras group hellas a. Overview the nace international task group t816 conducted an organized study on the cracking of refinery pressure vessels operating in wet h2s service. Stress corrosion cracking commonly occurs in brass, steels, stainless steels, aluminum alloys, copper, and titanium.
Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Ultrasonic testing for hydrogen induced and stress corrosion cracking in the oil and gas industry. The failure of highstrength fasteners in aerospace equipment as a result of scc or hsc occurs infrequently and almost always unexpectedly. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. Also referred to as hydrogen induced cold cracking, hydrogen cracking and delayed cracking, it requires the following during welding. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. The ductility loss brought about by hydrogen ingress is encountered even in unstressed bodies where such cracking is termed. The term environmental stress cracking1 failures is also used sometimes. Hydrogenassisted cracking models of steel for the oil and. This type of cracking has historically been associated with a514 t1 steel due to the combination of high strength material and the insufficient control of hydrogen during fabrication welding. A proposal procedure to estimate the hydrogen induced. The occurrence of hydrogen embrittlment is a much researched phenomenon, known to cause mechanical property degradation and catastrophic failures.
Defects hydrogen cracks in steels identification twi. Monitoring for hydrogen induced corrosion inspectioneering. Corrosionpedia what is hydrogeninduced cracking hic. It is manifested as blisters or blister cracks oriented parallel to the plate surface. Hydrogen embrittlement, caused by corrosion reaction in the condition of wet hydrothion, has brought many problems to industrial production. The first type is commonly referred to as hydrogeninduced cracking hic and can occur where little or no applied or residual tensile stress exists. This paper describes the implementation of ultrasonic scanning as an effective tool for the detection and monitoring of service induced damage to sour service. Rosen 15 types of pipeline cracks inspection solutions. Hic sohic hydrogen induced stress oriented hydrogen induced cracking detection using autpa technology. Occurrence and prevention of hydrogen induced stepwise. Practical solutions presents a functional approach to the various forms of corrosion, such as uniform corrosion, pitting corrosion, crevice corrosion, galvanic corrosion, stress corrosion, hydrogen induced damage, sulphide stress cracking, erosioncorrosion, and corrosion fatigue in various industrial environments. Hydrogeninduced cracking hic can occur in susceptible steels exposed to aqueous environments containing hydrogen sulphides. Improve crack detection and crack size measurement through ndt.
It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Axial crack inspection pipeline integrity management. Hic damage is a common degradation mechanism in the oil and gas industry. The principal distinguishing feature of this type of crack is that it occurs in ferritic steels, most often immediately on welding or a short time after welding. In cmn steels, because there is a greater risk of forming a brittle microstructure in the haz, most of the hydrogen cracks are to be found in the parent metal. In many cases, scc is really hydrogen induced stress cracking. Hydrogen blistering a special case of hydrogen damage is known as hydrogen blistering. The second type produces an array of blister cracks linked. These vessels are periodically subject to nondestructive evaluation, typically ultrasonic testing. Hydrogen cracking may also be called cold cracking or delayed cracking. Typical detection with phasedarray is done with l0 electronic scanning which cannot see the connections.
The conventional method for detecting wet h2s cracking is wet fluorescent. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by. Examples of hydrogen embrittlement are cracking of weldments or hardened steels when exposed to conditions which inject hydrogen into the component. Hydrogen induced cracking hic testing elements hic tests evaluate material susceptibility to hydrogen induced cracking in a sour environment in accordance with nace tm0284. The blistering damage tends to form parallel to the. Hydrogeninduced cracking hic can occur in susceptible. The following details non destructive inspection techniques aimed at identifying, quantifying and tracking this form of damage. The assessment of hydrogen induced crack hic defects have been developed procedures to determine the integrity in terms of remaining. New concept for cathodic protection of offshore pipelines. Corrosion prevention and protection wiley online books. Hydrogen induced cracking hic damage is a degradation mechanism active in the oil and gas industry.
Detection, characterization and sizing of hydrogen induced cracking in. Pdf sulfide stress corrosion cracking and hydrogen. Hydrogen cracking its causes, costs and future occurrence. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Ultrasonic detection of hydrogen induced cracking hic. It is caused by the diffusion of hydrogen to the highly stressed, hardened part of the weldment. Metallurgical evaluation of these cracks determined that they were consistent with hydrogen induced cracking. There is a need for highskilled engineers in integrity assessment where modeling for hydrogen degradation is concerned. Hydrogeninduced cracking and hydrogen embrittlement of. Hydrogen induced cracking hic is wet h2s cracking in steel in the form of blisters or blister cracks.
Nace standard tm02842003, evaluation of pipeline and pressure vessel steels for resistance to hydrogen induced cracking houston, tx. Detection of hydrogeninduced cracking hic olympus ims. Elements hic tests evaluate material susceptibility to hydrogen induced cracking in a sour environment in accordance with nace tm0284. Encoded data is collected, stored and be exported for. Weld overlay and conformal plate cladding technologies have been employed to mitigate these mechanisms by surface alloy enhancement.
Using advanced backscatter techniques htha can be identified at early stages prior to failure. The different requirements for the inspection of each mechanism hicsohic and monitoring techniques are. Detection of hydrogen induced cracks during inservice. Stress corrosion cracking and hydrogen embrittlement of. Ultrasonic detection of hydrogen induced cracking hic in. The paper looks at the problem of hydrogen cracking both in general fabrication and with particular reference to. The hydrogen atom is the smallest of all atoms and hydrogen attack is similarly insidious and hidden from simple inspection techniques. Engineering materials are exposed to hydrogen and they may interact with it resulting in various kinds of structural damage.
This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. Detection, characterization and sizing of hydrogen induced cracking. There are at least three factors which, with respect to influencing the risk of hydrogen cracking, can be considered specific to girth welds in pipe. Ultrasonic detection of hydrogen induced cracking hic in oil and gas industry panagiotis fousianis, dr. Gaseous hydrogen embrittlement of materials in energy. The determination of local enrichments of the hydrogen concentration in different microstructural regions of a steel or highstrength metallic component is required to reveal the underlying mechanisms for hydrogen induced stress cracking in critical manufactured zones like welds susceptible to hydrogen embrittlement. Nace standard sp02962010, detection, repair, and mitigation of cracking in refinery equipment in. Hydrogen induced crack initiated and arrested in an indentation specimen. Most hydrogen induced cracking hic in high strength quenchedandtempered ferritic steels occurs along prior austenite grain boundaries. Accurately detecting and evaluating corrosion depth, length and location. Phased array pa ultrasonic is the latest technology more and. An effective finite element model for the prediction of hydrogen induced cracking in steel pipelines, international journal of hydrogen energy volume 37, issue 21. A unified modeling of hydrogen induced cracking in steel pipelines, saudi aramco journal of technology. Typical detection with phasedarray is done with l0 electronic scanning which cannot see the connections between the cracks.
In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. Stresscorrosion cracking scc hydrogen induced cracking hic thermal andor mechanical fatigue. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Empa joining technologies and corrosion local hydrogen.
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